35 C 1 NQR and X - Ray Studies of Hexachloropalladates A 2 PdCl

نویسندگان

  • Peter Storck
  • Alarich Weiss
چکیده

The 35C1 NQR frequencies o f A 2PdCl6 were studied. For A = (CH3)4N + a clathrate [(CH3)4N]2PdCl6 Cl2 was found and its crystal structure was determined (F d3c, Z = 32, a = 2554.5 pm, R = 0.062). The clathrate [(CH3)4N]2SnCl6 Cl2 was prepared, too. It is isomorphous with the corresponding palladium salt. The results o f the 35C1 NQR studies are discus­ sed on the basis o f the crystal structure.

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تاریخ انتشار 2013